78350-73-9Relevant academic research and scientific papers
Complexes of 2-Phenylamino-5-carboxymethylthio-1,3,4-thiadiazole with Mn(II), Fe(II), Co(II) , Ni(II) and Cu(II)
Srivastava, R. S.,Yadav, L. D. S.,Khare, R. K.,Srivastava, A. K.
, p. 516 - 518 (2007/10/02)
2-Phenylamino-5-carboxymethylthio-1,3,4-thiadiazole forms complexes with divalent manganese, iron, cobalt, nickel and copper.The complexes have 2:1 (ligand-metal) stoichiometry.Cu(II) complex is square-planar while the rest are high-spin octahedral involving covalent bonding through the oxygen of COOH group and coordination through sulphur of exocyclic C-S group.The complexes are more fungitoxic against Paecilomyces variotii and Curvularia lunata, as compared to the ligand.
