78388-20-2

Basic information

• Product Name: 9-phenyl-9H-fluoren-9-yl (4-methylphenyl)sulfonylamidosulfite
• Synonyms: 9-phenyl-9H-fluoren-9-yl (4-methylphenyl)sulfonylamidosulfite
• CAS NO: 78388-20-2
• Molecular Formula: C₂₆H₂₁NO₄S₂
• Molecular Weight: 475.57924
• Mol File: 78388-20-2.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 9-phenyl-9H-fluoren-9-yl (4-methylphenyl)sulfonylamidosulfite(CAS DataBase Reference)
• NIST Chemistry Reference: 9-phenyl-9H-fluoren-9-yl (4-methylphenyl)sulfonylamidosulfite(78388-20-2)
• EPA Substance Registry System: 9-phenyl-9H-fluoren-9-yl (4-methylphenyl)sulfonylamidosulfite(78388-20-2)

Safety Data

• Hazardous Substances Data: 78388-20-2(Hazardous Substances Data)

Upstream product

• 25603-67-2 9-phenyl-fluoren-9-ol 
• 4104-47-6 N-sulfinyl-p-toluenesulfonamide 

Downstream Products

• 78388-16-6 N-(9-phenyl-9-fluorenyl)toluenesulfonamide 
• 56849-87-7 9-methoxy-9-phenylfluorene 
• 70-55-3 toluene-4-sulfonamide 

Relevant articles and documents

REACTIONS OF N-SULFINYL-p-TOLUENESULFONAMIDE WITH ALCOHOLS

N-Sulfinyl-p-toluenesulfonamide (1) reacted with triaryl- and diarylmethanols to give predominantly N-substituted sulfonamides and SO2 presumably via carbonium ion intermediates.When carbonium ion forming alcohols, such as t-BuOH and Ph2C(Me)OH, were used, the predominant products were alkenes and p-toluenesulfonamide.Allylic alcohols afforded N-substituted sulfonamides, along with dienes and p-toluenesulfonamide.Alcohols wich could not predictably give relatively stable intermediate carbonium ions, gave either dialkyl sulfites or dialkyl ethers, along with p-toluenesulfonamide.In one case, namely with 9-phenylfluorenol, the 1:1 adduct with 1 (an amidosulfite) was isolated.A mechanism for the reaction is proposed.