78400-57-4Relevant academic research and scientific papers
Direct synthesis of diallyl sulfides from allyl alcohols and hexamethyldisilathiane
Tsay, Shwu-Chen,Yep, Gregory L.,Chen, Buh-Luen,Lin, Lung Ching,Hwu, Jih Ru
, p. 8969 - 8976 (2007/10/02)
Diallyl sulfides were obtained in 60-90% yields by reaction of various allyl alcohols (1.0 equiv) with hexamethyldisilathiane (≈0.55 equiv) in CH2Cl2 at room temperature in the presence of BF3·OEt2 (0.8-1.1 equiv).
ELECTROPHILIC THIYLATION OF CONJUGATED DIENES BY HYDROGEN SULFIDE AND 1-BUTANETHIOL
Tolstikov, G. A.,Kanzafarov, F. Ya.,Sangalov, Yu. A.,Zelenova, L. M.,Vyrypaev, E. M.
, p. 203 - 211 (2007/10/02)
Alkylaluminium dihalides are selective catalysts for the addition of hydrogen sulfide and thiols to linear and cyclic 1,3-dienes.The thiylation of butadiene, isoprene, 2,3-dimethylbutadiene, E- and Z-1,3-pentadienes, 2,4-hexadiene, cyclopentadiene, cycloh
