78409-10-6

Upstream product

• 72856-29-2 4,5-dihydro-6H-1,3-thiazine 
• 52421-65-5 N,N-dimethyl-N'-thiobenzoylformamidine 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 122887-12-1 (2R,2aS,4aR,7aS)-2-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-1-oxo-2a-phenyl-2,2a,5,7a-tetrahydro-1H-3-thia-5,6,7b-triaza-cyclobuta[e]indene-4a-carboxylic acid methyl ester 
• 123314-79-4 (6R,7S)-7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-8-oxo-6-phenyl-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-3-carboxylic acid methyl ester 
• 123314-68-1 2-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-2a-phenyl-2,2a,4,7-tetrahydro-6-oxa-3-thia-7b-aza-cyclobuta[e]indene-1,5-dione 
• 123314-64-7 7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-2-methyl-8-oxo-6-phenyl-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-3-carboxylic acid methyl ester 
• 123314-70-5 7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-2-[1-hydroxy-meth-(E)-ylidene]-8-oxo-6-phenyl-5-thia-1-aza-bicyclo[4.2.0]oct-3-ene-3-carboxylic acid methyl ester 
• 122887-11-0 7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-2-formyl-8-oxo-6-phenyl-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-3-carboxylic acid methyl ester 
• 123314-66-9 2-Bromomethyl-7-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-8-oxo-6-phenyl-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-3-carboxylic acid methyl ester 
• 122887-13-2 7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-2-formyl-8-oxo-6-phenyl-5-thia-1-aza-bicyclo[4.2.0]octane-3-carboxylic acid methyl ester 
• 122887-10-9 2-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-1-oxo-2a-phenyl-2,2a,7,7a-tetrahydro-1H-3-thia-5,6,7b-triaza-cyclobuta[e]indene-4a-carboxylic acid methyl ester 
• 123314-72-7 7-Bromo-2-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-1-oxo-2a-phenyl-2,2a,7,7a-tetrahydro-1H-3-thia-5,6,7b-triaza-cyclobuta[e]indene-4a-carboxylic acid methyl ester 
• 123314-77-2 7-Bromo-2-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-1-oxo-2a-phenyl-2,2a,5,7a-tetrahydro-1H-3-thia-5,6,7b-triaza-cyclobuta[e]indene-4a-carboxylic acid methyl ester 
• 123314-67-0 7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-2-nitrooxymethyl-8-oxo-6-phenyl-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-3-carboxylic acid methyl ester 
• 123314-74-9 2-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-1-oxo-2a-phenyl-7-phenylselanyl-2,2a,7,7a-tetrahydro-1H-3-thia-5,6,7b-triaza-cyclobuta[e]indene-4a-carboxylic acid methyl ester 
• 122887-11-0 (6R,7S)-7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-2-formyl-8-oxo-6-phenyl-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-3-carboxylic acid methyl ester 

Relevant academic research and scientific papers

SELECTIVE SYNTHESIS OF SUBSTITUTED 6H-1,3-THIAZINES

(4+2)cyclocondensation reactions under high pressure between methylacrylate and 2-substituted 1-thia 3-aza 4-aminobutadienes leads selectively to 2-substituted 5-methoxycarbonyl 6H-1,3-thiazines.

Reduction Regioselective de Phenyl-2 6H-Thiazines-1,3 Substituees en 5 par des Groupements Fonctionnels Electroattracteurs

Sodium cyanoborohydride, triethylsilane (acidic medium), and aluminium amalgam (basic medium) regioselectively reduce the intracyclic imine group whereas sodium borohydride transforms the carbonyl fonction at position 5 into an alcohol.