784124-04-5Relevant academic research and scientific papers
New dinuclear thiobenzoato complexes of molybdenum(V) containing Mo2O2S2 core. X-ray crystal structures of [Mo2O2S2(OSCC6H5) 2(py)2] and [Mo2O2S2(OSCC6H5) 2(γ-pic)2]·2H2O
Cindric, Marina,Vrdoljak, Visnja,Prugovecki, Biserka,Kamenar, Boris
, p. 3321 - 3325 (1998)
The [Mo2O2S2(OSCC6H5) 2] (1) has been prepared either by the reaction of [Mo2O3(C5H7O2) 4] or of [Mo4Cl2O6(O2CCH3) 6]·(CH3CO)2O with thiobenzoic acid. The product was then used to prepare two complexes of the general formula [Mo2O2S2(OSCC6H5) 2L2] (where L = pyridine (2) or γ-picoline (3)). All complexes were characterized by elemental analyses, IR spectra and magnetic measurements. The structures of (2) and (3) were proved by X-ray structure analysis. Both complexes are dinuclear containing Mo2O2S2 core with two Mo atoms linked by a Mo-Mo single bond. The Mo atoms are octahedrally coordinated by oxo-oxygen, two bridging sulfido-sulfurs, one pyridine (or γ-picoline)-nitrogen and thiobenzoato-sulfur and thiobenzoato-oxygen atoms.
