784153-70-4Relevant academic research and scientific papers
Synthesis and characterization of new copper(I) complexes containing thione derivatives of 1,2,4-triazine. Crystal structure of [Cu(PPh3) 2(ATTO)]NO3 (ATTO = 4-amino-1,2,4-triazin-3(2H)-thione-5- one)
Yazdanbakhsh, Mohammad,Hakimi, Mohammad,Heravi, Majid M.,Ghassemzadeh, Mitra,Neumueller, Bernhard
, p. 627 - 629 (2004)
The reaction of 4-amino-1,2,4-triazin-3(2H)-thione-5-one (ATTO, 1) with [Cu(PPh3)2]NO3 in ethanol led to the complex [Cu(PPh3)2(ATTO)]NO3 (2). 2 was characterized by elemental analyses, IR, 1H NMR and Raman spectroscopy. A single-crystal X-ray diffraction of compound 2 revealed that ATTO acts as a bidentate ligand via its nitrogen and sulfur atoms. Crystal data for 2 at 20°C: space group P21/n with a = 975.7(1), b = 1533.5(2), c = 2504.2(3) pm, β = 92.25(1)°, Z = 4, R1 = 0.0632.
