78423-66-2

Upstream product

• 538-37-4 dibenzyl phosphochloridate 
• 83236-99-1 3,4,6-tri-O-acetyl-2-deoxy-2-tetradecanoylamino-α-D-glucopyranose 
• 79940-52-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-amino-6-(bis-benzyloxy-phosphoryloxy)-tetrahydro-pyran-4-yl ester 
• 112-64-1 tetradecanoyl chloride 
• 1623-08-1 phosphoric acid dibenzyl ester 
• 74660-51-8 2-(tridecyl)-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyrano)-<2,1-d>-2-oxazoline 
• 79940-50-4 dibenzyl tributylstannyl phosphate 
• 51884-88-9 3,4,6-tri-O-acetyl-2-deoxy-2-(p-methoxybenzylideneamino)-α-D-glucopyranosyl bromide 
• 79940-51-5 Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-(bis-benzyloxy-phosphoryloxy)-5-{[1-(4-methoxy-phenyl)-meth-(E)-ylidene]-amino}-tetrahydro-pyran-4-yl ester 
• 74660-48-3 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-6-allyloxy-5-tetradecanoylamino-tetrahydro-pyran-4-yl ester 

Relevant academic research and scientific papers

A CONVENIENT PREPARATIVE METHOD OF CARBOHYDRATE PHOSPHATES WITH BUTYLLITHIUM AND PHOSPHOROCHLORIDATE

α-Glycosyl phosphates and 4-phosphates of N-acylglucosamine derivatives were prepared in high yields via the reaction of corresponding O-lithium salts with dibenzyl or diphenyl phosphorochloridate at low temperature.

Synthesis of 2-(Acylamino)-2-deoxy-α-D-glucopyranosyl Phosphates: Monosaccharide Analogs of Lipid A

3,4,6-Tri-O-acetyl-2--2-deoxy-α-D-glucopyranosyl phosphates (13 - 16; monosaccharide analogs of lipid A) were synthesized from the corresponding 2-(tri-, penta-, hepta- and nona-decyl)-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyrano)--2-oxazolines (5 - 8).