78426-31-0

Basic information

• Product Name: 2-Cyclohexene-1-methanol, 2-methyl-
• CAS NO: 78426-31-0
• Molecular Formula: C8H14O
• Molecular Weight: 126.199
• Mol File: 78426-31-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexene-1-methanol, 2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexene-1-methanol, 2-methyl-(78426-31-0)
• EPA Substance Registry System: 2-Cyclohexene-1-methanol, 2-methyl-(78426-31-0)

Safety Data

• Hazardous Substances Data: 78426-31-0(Hazardous Substances Data)

Upstream product

• 71353-96-3 6-Methyl-7-oxa-bicyclo[4.2.0]octane 
• 107-07-3 2-chloro-ethanol 
• 50-00-0 formaldehyd 
• 591-49-1 1-methylcyclohex-1-ene 
• 75-24-1 trimethylaluminum 

Relevant articles and documents

Nucleophilic displacement of homoallylic tosylates: Influence of steric hindrance and conformational rigidity

A comparative study on the nucleophilic displacement of homoallylic tosylates with different degrees of hindrance and rigidity is reported. π Bond participation is favoured by hindrance and rigidity, and also by weak nucleophiles such as water or dimethylformamide.

Formaldehyde Encapsulated in Zeolite: A Long-Lived, Highly Activated One-Carbon Electrophile to Carbonyl-Ene Reactions

Gaseous formaldehyde is extremely unstable and readily undergoes self-polymerization to a solid paraformaldehyde or disproportionation to methanol and formic acid in the presence of moisture. We disclose a simple method to stably store such a labile formaldehyde as a monomer in a nanoporous faujasite zeolite at 5 °C for at least 50 days without self-polymerization or disproportionation. The greater stability of formaldehyde encapsulated in zeolite was confirmed by 13C MAS NMR spectroscopy. Formaldehyde was not only stabilized within the zeolite cages but functioned as a powerful electrophile toward various olefins. Zeolite-encapsulated formaldehyde was proved to be a stable but highly reactive C1 reagent. Copyright

DIMETHYLALUMINUM CHLORIDE CATALYZED ENE REACTIONS OF ALDEHYDES.

Dimethylaluminum chloride, which is a mild Lewis acid and a proton scavenger, catalyzes the ene reactions of aliphatic and aromatic aldehydes with alkenes containing a disubstituted vinylic carbon. Proton-initiated rearrangements do not occur, since the alcohol-Lewis acid complex formed in the ene reaction reacts rapidly to give methane and a nonacidic aluminum alkoxide. Formaldehyde and excess Me//2AlCl give good yields of ene adducts with all types of alkenes. With 1 equiv of Me//2AlCl, formaldehyde and mono- and 1,2-disubstituted alkenes give gamma -chloro alcohols resulting from cis addition of chlorine and hydroxymethyl groups to the double bond. This work is pertinent to the synthesis of alcohols.