78426-62-7Relevant academic research and scientific papers
ANTIMONY-121 MOESSBAUER AND INFRARED SPECTRAL STUDY ON HALOPHENYLANTIMONATE(III) COMPOUNDS
Alonzo, G.,Bertazzi, N.,Bianca, F. Di,Gibb, T.C.
, p. 63 - 68 (2007/10/02)
The synthesis and the 121Sb Moessbauer and infrared spectra of the halophenylantimonates(III) M (M=Me4N, Ph4As; X=Cl, Br, I) are reported, and the spectral data are discussed and compared with those of SbX-4 and other related systems.The results are in accord with the participation of the antimony 5s electrons in the Sb-Ph bond.In the interpretation of the electric field gradient, the contributions to Vzz from both the lone pair and the Sb-Ph bond electron densities are assumed to be dominant.
