78430-93-0Relevant academic research and scientific papers
Highly stable N3-substituted imidazolium-based alkaline anion exchange membranes: Experimental studies and theoretical calculations
Gu, Fenglou,Dong, Huilong,Li, Youyong,Si, Zhihong,Yan, Feng
, p. 208 - 216 (2014)
Imidazolium cations with various N3-substituents (including methyl, butyl, heptyl, dodecyl, isopropyl, and diphenylmethyl groups) were synthesized and investigated in terms of their alkaline stability. The effect of the N3-substituent on the alkaline stab
Highly efficient aqueous phase chemoselective hydrogenation of α,β-unsaturated aldehydes catalysed by phosphine-decorated polymer immobilized IL-stabilized PdNPs
Doherty,Knight,Backhouse,Abood,Alshaikh,Fairlamb,Bourne,Chamberlain,Stones
supporting information, p. 1635 - 1641 (2017/06/05)
Phosphino-decorated polymer immobilised ionic liquid phase stabilised palladium nanoparticles (PdNP@PPh2-PIILP) and their PEGylated counterparts (PdNP@PPh2-PEGPIILP) are remarkably active and exceptionally selective catalysts for the aqueous phase hydrogenation of α,β-unsaturated aldehydes, ketones, esters and nitriles with PdNP@PPh2-PEGPIILP giving complete conversion and 100% selectivity for reduction of the CC bond, under mild conditions. This is the most selective PdNP-based system to be reported for the aqueous phase hydrogenation of this class of substrates.
