78442-59-8

Upstream product

• 94273-27-5 2,5-anhydro-3,4,6-tris-O-(phenylmethyl)-D-mannose 
• 66149-72-2 3-[O⁵-(tert-butyl-dimethyl-silanyl)-O²,O³-isopropylidene-β-D-ribofuranosyl]-pyrrole-2,5-dione 
• 78442-67-8 3-[(3aR,4R,6S,6aS)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-pyrrole-2,5-dione 
• 142968-15-8 3-[1-Methoxycarbonyl-meth-(E)-ylidene]-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester 
• 75467-23-1 2-(2',3'-di-O-methoxymethyl-5'-O-tert-butyldimethylsilyl-β-D,L-arabinofuranosyl)maleimide 
• 75467-21-9 methyl 2-(2',3'-di-O-methoxymethyl-5'-O-tert-butyldimethylsilyl-β-D,L-arabinofuranosyl) glyoxylate 
• 75467-16-2 methyl 2-(2',3'-di-O-methoxymethyl-5'-O-tert-butyldimethylsilyl-β-D,L-arabinofuranosyl) glycolate 
• 75467-14-0 methyl 2-(2',3'-di-O-methoxymethyl-β-D,L-arabinofuranosyl) glycolate 
• 66268-91-5 [(3aS,4S,6S,6aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-oxo-acetic acid methyl ester 
• 75467-31-1 [(3aR,4R,6S,6aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-hydroxy-acetic acid methyl ester 
• 75467-29-7 Hydroxy-((3aR,4R,6S,6aS)-6-hydroxymethyl-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-acetic acid methyl ester 
• 78442-65-6 2-[(3aR,4R,6S,6aS)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-3-cyano-propionic acid methyl ester 
• 78442-66-7 3-[(3aR,4R,6S,6aS)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-pyrrolidine-2,5-dione 
• 78442-64-5 (3aS,4S,6S,6aS)-6-(2-Cyano-1-methoxycarbonyl-ethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole-4-carboxylic acid 

Relevant academic research and scientific papers

REACTION BETWEEN GLYCAL BENZYL ETHERS AND THALLIUM(III) NITRATE. SYNTHESIS OF SHOWDOMYCIN ANALOGUES.

On treatment with thallium(III) nitrate, trihydrate in acetonitrile solution, 3,4,6-tri-O-benzyl-D-glucal (5) gives the ring-contracted aldehyde (6) which has been converted into the showdomycin analogue (8) ; 2-(α-D-2'-deoxyribofuranosyl)maleimide (12) h