78488-87-6

Upstream product

• 528-76-7 2,4-dinitrobenzenesulfenyl chloride 
• 18522-92-4 sodium p-toluenesulfonamide 

Downstream Products

• 78488-92-3 C₁₃H₁₀N₃O₆S₂^(1-)*Na⁽¹⁺⁾ 
• 105897-02-7 C₂₀H₁₈N₄O₈S₃ 
• 105897-01-6 C₁₉H₁₆N₄O₈S₃ 

Relevant academic research and scientific papers

Oxidative alkoxylation of N-arylsulfonyl-2,4-dinitrobenzenesulfenamides. Alkyl esters of N-arylsulfonyl-2,4-dinitrobenzeneiminosulfinic acids

Upon α-N-anionic activation of the sulfur atom N-arylsulfonyl-2,4-dinitrobenzenesulfenamides relatively readily undergo oxidative alkoxylation with formation of alkyl esters of N-arylsulfonyl-2,4-dinitrobenzeneiminosulfinic acids. The esters synthesized a

IMINATION OF SULFUR-CONTAINING COMPOUNDS. XIV. ARYLSULFONYLIMINATION OF N-ARYLSULFONYL-2,4-DINITROBENZENE- AND N-ARYLSULFONYL-2,4,6-TRINITROBENZENESULFENAMIDES

N-Alkyl-N-arylsulfonyl-2,4-dinitrobenzenesulfenamides are not iminated by N-sodio-N-chlorosulfonamides.This is due to the impossibility of the formation of the mesomeric anion of the N-arylsulfonyl-2,4-dinitrobenzenesulfenamide.N-Arylsulfonyl-2,4-dinitrobenzenesulfenamides are smoothly iminated by N-sodio-N-chlorosulfonamides in polar media with the formation of N,N'-bis(arylsulfonyl)-2,4-dinitrobenzenesulfinamidines.In spite of the high stability of the mesomeric anion of the N-arylsulfonyl-2,4,6-trinitrobenzenesulfenamide, it was not possible to realize its imination.This is clearly due to the steric factor or to the weak nucleophilicity of the iminated sulfur.