78571-83-2Relevant academic research and scientific papers
Dynamic kinetic asymmetric transformations of β-stereogenic α-ketoesters by direct aldolization
Corbett, Michael T.,Johnson, Jeffrey S.
, p. 255 - 259 (2014)
Dynamic kinetic asymmetric transformations (DyKAT) of racemic β-bromo-α-keto esters by direct aldolization of nitromethane and acetone provide access to fully substituted α-glycolic acid derivatives bearing a β-stereocenter. The aldol adducts are obtained
Selective C-2 opening of 2,3-epoxyesters with HN3-amine system: A viable route to β-hdyroxy-α-amino acids
Saito,Takahashi,Ishikawa,Moriwake
, p. 667 - 670 (2007/10/02)
The combination of hydrogen azide with amines has proven to effect the C-2 opening of 2,3-epoxyester with high regioselectivity uniformly for trans-epoxyesters and depending on their structures for cis-2,3-epoxyesters.
