78574-08-0

Basic information

• Product Name: 3-(4-TERT-BUTYL-PHENYL)-PROPAN-1-OL
• Synonyms: 3-(4-TERT-BUTYL-PHENYL)-PROPAN-1-OL
• CAS NO: 78574-08-0
• Molecular Formula: C₁₃H₂₀O
• Molecular Weight: 192.2973
• Mol File: 78574-08-0.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 291°C at 760 mmHg
• Flash Point: 114.5°C
• Appearance: /
• Density: 0.947g/cm³
• Vapor Pressure: 0.000919mmHg at 25°C
• Refractive Index: 1.506
• CAS DataBase Reference: 3-(4-TERT-BUTYL-PHENYL)-PROPAN-1-OL(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-TERT-BUTYL-PHENYL)-PROPAN-1-OL(78574-08-0)
• EPA Substance Registry System: 3-(4-TERT-BUTYL-PHENYL)-PROPAN-1-OL(78574-08-0)

Safety Data

• Hazardous Substances Data: 78574-08-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H20O/c1-13(2,3)12-8-6-11(7-9-12)5-4-10-14/h6-9,14H,4-5,10H2,1-3H3

Upstream product

• 260-94-6 acridine 
• 24475-36-3 4-[4-(1,1-dimethylethyl)phenyl]butanoic acid 
• 75-21-8 oxirane 
• 939-97-9 4-tert-Butylbenzaldehyde 
• 64-17-5 ethanol 
• 877-65-6 p-tert-butylbenzyl alcohol 
• 1208-64-6 3-(4-tert-butylphenyl)propionic acid 
• 18880-00-7 1-(bromomethyl)-4-(1,1-dimethylethyl)benzene 
• 37765-76-7 2-(4-tert-butylbenzyl)diethylmalonate 
• 130872-28-5 ethyl 3-(4-(tert-butyl)phenyl)propanoate 
• 1211-99-0 3-(4-tert-butyl-phenyl)propionic acid methyl ester 

Downstream Products

• 141499-24-3 4-(3-bromopropyl)-1-(1,1-dimethylethyl)benzene 
• 18127-01-0 3-(4-tert-butylphenyl)propionaldehyde 
• 1174295-77-2 C₂₆H₃₆F₂O₇S 
• 1174295-76-1 C₃₀H₄₆O₇S 
• 1174295-75-0 C₂₆H₃₈O₅S 

Relevant articles and documents

Access to Trisubstituted Fluoroalkenes by Ruthenium-Catalyzed Cross-Metathesis

Although the olefin metathesis reaction is a well-known and powerful strategy to get alkenes, this reaction remained highly challenging with fluororalkenes, especially the Cross-Metathesis (CM) process. Our thought was to find an easy accessible, convenient, reactive and post-functionalizable source of fluoroalkene, that we found as the methyl 2-fluoroacrylate. We reported herein the efficient ruthenium-catalyzed CM reaction of various terminal and internal alkenes with methyl 2-fluoroacrylate giving access, for the first time, to trisubstituted fluoroalkenes stereoselectively. Unprecedent TON for CM involving fluoroalkene, up to 175, have been obtained and the reaction proved to be tolerant and effective with a large range of olefin partners giving fair to high yields in metathesis products. (Figure presented.).

Palladium-catalyzed double-bond migration of unsaturated hydrocarbons accelerated by tantalum chloride

The operationally simple palladium-catalyzed double-bond migration without heteroatom-containing coordinating functional groups is described. Addition of TaCl5 as a second catalyst greatly enhanced the migration efficiency to provide β-alkylsty

Anodic benzylic C(sp3)-H amination: Unified access to pyrrolidines and piperidines

An electrochemical aliphatic C-H amination strategy was developed to access the important heterocyclic motifs of pyrrolidines and piperidines within a uniform reaction protocol. The mechanism of this unprecedented C-H amination strategy involves anodic C-H activation to generate a benzylic cation, which is efficiently trapped by a nitrogen nucleophile. The applicability of the process is demonstrated for 40 examples comprising both 5- and 6-membered ring formations.