785804-07-1Relevant academic research and scientific papers
A mechanistic analysis of the Rh-catalyzed intramolecular C-H amination reaction
Fiori, Kristin Williams,Espino, Christine G.,Brodsky, Benjamin H.,Du Bois
experimental part, p. 3042 - 3051 (2009/09/27)
A detailed mechanistic investigation of the intramolecular dirhodium tetracarboxylate-catalyzed sulfamate ester C-H amination reaction is presented. These studies provide support for the formation of a sulfamate-derived iminoiodinane, which reacts rapidly
RH-catalyzed animation of ethereal Cα-H bonds: A versatile strategy for the synthesis of complex amines
Fiori, Kristin Williams,Fleming, James J.,Du Bois, Justin
, p. 4349 - 4352 (2007/10/03)
Intramolecular C-H insertion with sulfamates catalyzed by rhodium complexes offers an effective method for the preparation of N,O-acetals, which function as iminium ion precursors and undergo smooth diastereoselective coupling with nucleophiles under Lewi
