78590-01-9

Upstream product

• 92850-41-4 8-hydroxy-2-phenyl-5,6,7,8-tetrahydroquinoline 

Downstream Products

• 887922-07-8 (R)-8-hydroxy-2-phenyl-5, 6, 7, 8-tetrahydroquinoline 
• 887922-03-4 (8S)-2-phenyl-8-hydroxy-5,6,7,8-tetrahydroquinoline 
• 97112-07-7 2,8-Diphenyl-5,6,7,8-tetrahydro-quinolin-8-ol 
• 97112-06-6 8-Methyl-2-phenyl-5,6,7,8-tetrahydro-quinolin-8-ol 
• 92850-41-4 8-hydroxy-2-phenyl-5,6,7,8-tetrahydroquinoline 
• 1373403-55-4 2-phenyl-8-(2,4-dibenzhydryl-6-methylphenylimino)-5,6,7-trihydroquinoline 
• 1373403-63-4 2-phenyl-8-(2,6-dibenzhydryl-4-methylphenylimino)-5,6,7-trihydroquinoline 
• 1373403-66-7 2-phenyl-8-(2,6-dibenzhydryl-4-isopropylphenylimino)-5,6,7-trihydroquinoline 
• 1373403-59-8 2-phenyl-8-(2-benzhydryl-4,6-dimethylphenylimino)-5,6,7-trihydroquinoline 
• 1263563-99-0 [2,6-bis(1-methylethyl)-N-(2-phenyl-5,6,7-trihydroquinolin-8-ylidene)phenylamino]nickel(II) dichloride 
• 1263563-97-8 [2,6-dimethyl-N-(2-phenyl-5,6,7-trihydroquinolin-8-ylidene)phenylamino]nickel(II) dichloride 
• 1263564-03-9 [2,6-diethyl-4-methyl-N-(2-phenyl-5,6,7-trihydroquinolin-8-ylidene)phenylamino]nickel(II) dichloride 
• 1263564-01-7 [2,4,6-trimethyl-N-(2-phenyl-5,6,7-trihydroquinolin-8-ylidene)phenylamino]nickel(II) dichloride 
• 1263563-94-5 [2,6-dimethyl-N-(2-phenyl-5,6,7-trihydroquinolin-8-ylidene)phenylamino]nickel(II) dichloride 

Relevant academic research and scientific papers

Design and synthesis of new chiral pyridine-phosphite ligands for the copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones

A series of new chiral pyridine-phosphite ligands have been prepared from (R)-pyridyl alcohols and BINOL-derived chlorophosphite, and successfully employed in the copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones. Using the simple and inexpensive CuBr2 as a precursor, the enantioselective additions to various substituted acyclic enones afforded products in high yields and good enantioselectivities (up to 92% ee).

Applications of Organolithium and Related Reagents in Synthesis. Part 3. A General Study of the Reaction of Lithium Alkyls with Pyridine Ketones

The reaction of MeLi and PhLi with acetylpyridines (1a-c) and their annelated derivatives (2a), (2b), (3), and (4) has been examined.The 3- and 4-pyridyl ketones (1b), (1c), (3), and (4) gave similar results to acetophenone and 3,4-dihydronaphthalen-1(2H)-one.In the case of the 2-pyridyl ketones (1a), (2a), and (2b) unexpectedly low yields of products resulted from the addition of RLi to the carbonyl group; the reaction was efficiently enhanced by initially adding an additional amount of LiBr.These results were accounted for by the chelation of RLi or LiBr by the 2-pyridyl ketones.