78602-55-8Relevant academic research and scientific papers
Thioaldehyde S-Oxide (Monosubstituted Sulfines) from Thioacylsilane S-Oxides. Synthesis and Fluorine- and Acid-Induced Z/E Isomerization. 2
Barbaro, G.,Battaglia, A.,Giorgianni, P.,Bonini, B. F.,Maccagnani, G.,Zani, P.
, p. 3744 - 3748 (2007/10/02)
Aromatic and aliphatic, not enethiolizable, thioaldehyde S-oxides (monosubstituted sulfines) are obtained from stereospecific fluorodesilylation of the corresponding thioacylsilane S-oxides with retention of configuration.A detailed investigation on the mechanism of the desilylation, as well as of the acid and fluoride ion induced Z/E interconversion has been performed.
Synthesis and Isolation of Aryl Thioaldehyde S-Oxides
Bonini, Bianca F.,Mazzanti, Germana,Zani, Paolo,Maccagnani, Gaetano,Barbaro, Gaetano,et al.
, p. 964 - 965 (2007/10/02)
(E)-Phenyl and (E)-(p-tolyl) trimethylsilyl thioketone S-oxides can be easily and stereospecifically protodesilylated into the corresponding (Z)-aryl thioaldehyde S-oxides; these stable liquid lachrimatory compounds show good reactivity as heterodienophil
