78629-73-9Relevant academic research and scientific papers
Reactivity of BH3 and 9-BBN towards palladium(II) complexes of diphenylvinyl- and diphenylallyl-phosphine; X-ray structures of [PdCl2(PPh2CH2CH2CH 3)]2 and [PdCl2(PPh<
Coles, Simon J.,Faulds, Paul,Hursthouse, Michael B.,Kelly, David G.,Ranger, Georgia C.,Toner, Andrew J.,Walker, Neil M.
, p. 234 - 240 (2007/10/03)
Palladium(II) chloride complexes PdCl2L2 and [PdCl2L]2 have been prepared with the phosphine ligands PPh2CH=CH2 and PPh2CH2CH=CH2. The reactions of PdClsub
Complexes of Ph2PCH=CH2 with PtX2 (X = Cl, Br, I or Me) or PdX2 (X = Cl, Br or I)
Fontaine, Xavier L. R.,Markham, David P.,Shaw, Bernard, L.
, p. 123 - 129 (2007/10/02)
Treatment of Ph2PCH=CH2 with or with , gives cis-, which on treatment with LiBr gives the corresponding dibromide, or with NaI, the corresponding di-iodide.In dichloromethane solution, cis- partially isomerizes to give a cis/trans-mixture.Treatment of with Ph2PCH=CH2 gives cis-.Treatment of with Ph2PCH=CH2 gives a mixture of cis- and trans-, which with LiBr gives a similar mixture of the corresponding dibromides, while reaction with NaI gives trans-. 31P NMR and 1H- and 1H NMR, and IR spectroscopic data are given.
