78638-84-3

Basic information

• Product Name: 1-(α-Chlorbenzyl)adamantan
• CAS NO: 78638-84-3
• Molecular Weight: 260.807
• Mol File: 78638-84-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-(α-Chlorbenzyl)adamantan(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(α-Chlorbenzyl)adamantan(78638-84-3)
• EPA Substance Registry System: 1-(α-Chlorbenzyl)adamantan(78638-84-3)

Safety Data

• Hazardous Substances Data: 78638-84-3(Hazardous Substances Data)

Upstream product

• 281-23-2 adamantane 
• 74670-99-8 3-Chlor-3-phenyl-1,2-diaziridin 
• 19807-41-1 chlorophenylcarbene 
• 4460-46-2 3-chloro-3-phenyl-3H-diazirine 
• 98-87-3 benzylidene dichloride 

Relevant articles and documents

Remote substituent effects on phenylchlorocarbene C-H insertion reactions

Formula presented Phenylchlorocarbene inserts into the tertiary CH bonds of 1,3-dimethyladamantane and 1-X-adamantanes (X = H, OMe COOMe, Cl, CN). There is a good correlation between the relative rate constants for these insertions and the inductive subst

REACTIVITY AND SELECTIVITY IN INTERMOLECULAR INSERTION REACTIONS OF CHLOROPHENYLCARBENE

Reactivities for intermolecular C-H/Si-H/Sn-H insertion reactions of chlorophenylcarbene follow the order tri-n-butyltin hydride>>diphenylsilane>triethylsilane>>cumene>ethylbenzene>>toluene, and these reactions are competitive with addition to the double bond of α,β-unsaturated esters.