78672-64-7

Basic information

• Product Name: (±)-1,2,6,6-tetramethylcyclohex-2-ene-1-carbaldehyde
• Synonyms: (±)-1,2,6,6-tetramethylcyclohex-2-ene-1-carbaldehyde
• CAS NO: 78672-64-7
• Molecular Weight: 166.263
• Mol File: 78672-64-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (±)-1,2,6,6-tetramethylcyclohex-2-ene-1-carbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-1,2,6,6-tetramethylcyclohex-2-ene-1-carbaldehyde(78672-64-7)
• EPA Substance Registry System: (±)-1,2,6,6-tetramethylcyclohex-2-ene-1-carbaldehyde(78672-64-7)

Safety Data

• Hazardous Substances Data: 78672-64-7(Hazardous Substances Data)

Upstream product

• 432-25-7 2,6,6-trimethylcyclohex-1-enecarbaldehyde 
• 74-88-4 methyl iodide 
• 78672-63-6 1,2,2-trimethyl-6-methylene-cyclohexanecarbaldehyde 
• 73683-20-2 (2,2,6,6-Tetramethyl-cyclohexylidene)-methanone 
• 54439-96-2 2,2,6,6-Tetramethylcyclohexancarbonylchlorid 
• 78672-62-5 (1,2,2-trimethyl-6-methylene-cyclohexyl)-methanol 

Downstream Products

• 3949-35-7 1,2,3,3-tetramethylcyclohexene 
• 3757-05-9 1,5,5,6-tetramethyl-cyclohexene 
• 1846-45-3 1,1,2-Trimethyl-3-methylene-cyclohexane 

Relevant articles and documents

Deconjugative α-Alkylation of Cyclohexenecarboxaldehydes: An Access to Diverse Terpenoids

A general and efficient method for the deconjugative α-alkylation of α,β-unsaturated aldehydes promoted by a synergistic effect between tBuOK and NaH, which considerably increases the reaction rate under mild conditions, is reported. The β,γ-unsaturated aldehyde, resulting from the α-alkylation, is transformed in high yield into the corresponding allyl acetate via a lead(IV) acetate-mediated oxidative fragmentation. This strategy could be used for the construction of the carbon skeleton of a wide variety of alkyl or arylterpenoids.