787-34-8Relevant academic research and scientific papers
Synthesis of alkyl-aryl ethers by copper-catalyzed etherization reactions of aryl fluorides with tetraalkylammonium bromides and H2O
Wang, Feng,Tang, Boxiao,Xie, Yexiang,Li, Jinheng
experimental part, p. 2318 - 2322 (2011/10/03)
Synthesis of alkyl aryl ethers via copper-catalyzed etherizations of electron-deficient aryl fluorides with quaternary ammonium bromides and water has been developed. In the presence of Cu(OAc)2, POPh3 (L4) and Cs2CO3, a variety of electron-deficient aryl fluorides underwent the reaction with quaternary ammonium bromides and H 2O in moderate to good yields. The mechanism was also discussed. Synthesis of alkyl aryl ethers via copper-catalyzed etherizations of electron-deficient aryl fluorides with quaternary ammonium bromides and water has been developed. In the presence of Cu(OAc)2, POPh3 (L4) and Cs2CO3, a variety of electron-deficient aryl fluorides underwent the reaction with quaternary ammonium bromides and H 2O in moderate to good yields. Copyright
