78703-69-2Relevant academic research and scientific papers
OZONOLYSIS OF ALKENES AND REACTIONS OF POLYFUNCTIONAL COMPOUNDS. XXIX. SYNTHESIS OF ACYCLIC (Z)-1,5-POLYENE ISOPRENOID KETO ACETALS
Odinokov, V. N.,Ignatyuk, V. K.,Krivonogov, V. P.,Tolstikov, G. A.
, p. 848 - 851 (2007/10/02)
A convenient method was developed for the synthesis of acyclic (Z)-1,5-polyene isoprenoid keto acetals on the basis of the partial ozonolysis of regular (Z)-1,4-polyisoprene with subsequent reduction of the peroxides to ω-acetylaldehydes and selective protection of the formyl group.The individual dimethyl acetals of (Z)-1,5-polyene isoprenoid ω-acetylaldehydes with 1-5 (Z)-isoprene units were isolated by vacuum distillation of the mixture of isoprenologs.
