78705-63-2Relevant academic research and scientific papers
Reactivities of Stable Rotamers. X. Reactions of 9-(2-Formyl-1-naphthyl)fluorene Rotamers and Related Compounds
Saito, Ryo,Oki, Michinori
, p. 3267 - 3272 (2007/10/02)
Rotational barrier (ap -> sp) in 9-(2-formyl-1-naphthyl)fluorene was determined: ΔH(excit.) 24.0 kcal/mol and ΔS(excit.) -7.9 e.u.Oxidation of the aldehyde with chromium(VI) oxide was extremely slow in the ap form, whereas it proceeded smoothly in the sp
ISOLATION AND RELATIVE REACTIVITIES IN CHROMIUM(VI) OXIDE OXIDATION OF THE ROTAMERS OF 9-(2-FORMYL-1-NAPHTHYL)FLUORENE AND RELATED ALCOHOLS
Oki, Michinori,Saito, Ryo
, p. 649 - 652 (2007/10/02)
Rotational isomers (sp and ap) of 9-(2-formyl-1-naphthyl)fluorene were isolated. ΔH and ΔS for rotation (sp ap) were 24.0 kcal mol-1 and -7.9 e. u., respectively.Oxidation of the sp form afforded the correspondin
