78739-51-2Relevant academic research and scientific papers
Addition and Cycloaddition Reactions of Allenyl Cations with Acyclic 1,3-Dienes
Mayr, Herbert,Klein, Herbert
, p. 3528 - 3546 (2007/10/02)
The zinc chloride-ether catalysed reactions of propargyl halides 1 with acyclic dienes 2 at -78 deg C give linear addition products 3 and 4.At elevated temperature allyl chlorides 3 and 4 rearrange to vinyl chlorides 5 with Lewis acid catalysis.Only those
Zinc Chloride Catalyzed Addition Reactions of Propargyl Chlorides with Acyclic 1,3-Dienes
Mayr, Herbert,Klein, Herbert
, p. 4097 - 4100 (2007/10/02)
Zinc chloride catalyzed reactions of propargyl chlorides with acyclic 1,3-dienes (at -78 deg C) give linear addition products, which cyclize to 4-(chloroalkylidene)cyclohexenes at elevated temperature.
