78757-95-6Relevant academic research and scientific papers
Microwave induced bismuth trichloride catalysed Beckmann rearrangement of oximes
Thakur, Ashim J.,Boruah, Anima,Prajapati, Dipak,Sandhu, Jagir S.
, p. 2105 - 2111 (2000)
A new and efficient method for the rearrangement of oximes 1 has been achieved by a simple reaction of a ketoximes with bismuth trichloride under microwave irradiation in the solid state.
Indium trifluoromethanesulfonate (In(OTf)3)- A new catalyst for Beckmann rearrangement of ketoximes and facile dehydration of aldoximes
Barman, Dhiren C.,Gohain, Mukut,Prajapati, Dipak,Sandhu, Jagir S.
, p. 154 - 156 (2007/10/03)
Indium trifluoromethanesulfonate is found to be an effective catalyst for the facile dehydration of aldoximes to nitriles and Beckmann rearrangement of ketoximes to anilides in excellent yields.
TRIMETHYLSILYL POLYPHOSPHATE (PPSE). A USEFUL REAGENT FOR THE BECKMANN REARRANGEMENT
Imamoto, Tsuneo,Yokoyama, Hideki,Yokoyama, Masataka
, p. 1803 - 1804 (2007/10/02)
Various oximes were rearranged smoothly to the corresponding amides in trimethylsilyl polyphosphate (PPSE) which was conveniently prepared from phosphorus pentoxide and hexamethyldisiloxane.
