78814-30-9

Upstream product

• 64432-53-7 1-(phenylselanyl)cyclopropane-1-carbonitrile 
• 99440-99-0 2-hydroxycyclobutanone 
• 645-96-5 Benzeneselenol 
• 69930-99-0 1,1-(bisphenylseleno)cyclopropane 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 79011-91-9 [((Z)-1-Oct-1-enyl)-cyclopropylselanyl]-benzene 
• 78814-56-9 (1-Methylselanyl-cyclobutyl)-(1-phenylselanyl-cyclopropyl)-methanol 
• 78814-55-8 2-Methylselanyl-2-octyl-1-(1-phenylselanyl-cyclopropyl)-decan-1-ol 
• 78814-41-2 (1-Cyclobutylidenemethyl-cyclopropylselanyl)-benzene 
• 78814-40-1 [1-(2-Octyl-dec-1-enyl)-cyclopropylselanyl]-benzene 
• 78814-50-3 2-Phenylselanyl-1-(1-phenylselanyl-cyclopropyl)-octan-1-ol 
• 78814-49-0 2-Methylselanyl-1-(1-phenylselanyl-cyclopropyl)-octan-1-ol 

Relevant academic research and scientific papers

Acid-catalyzed synthesis of functionalized arylthio cyclopropane carbaldehydes and ketones

A general strategy for the synthesis of arylthio cyclopropyl carbaldehydes and ketones via a Br?nsted acid catalyzed arylthiol addition/ring contraction reaction sequence has been exploited. The procedure led to a wide panel of cyclopropyl carbaldehydes in generally high yields and with broad substrate scope. Mechanistic aspects and synthetic applications of this procedure were investigated.

REGIO AND STEREOSELECTIVE SYNTHESIS OF 1-METHYLSELENO-1-VINYL AND 1-PHENYLSELENO-1-VINYL CYCLOPROPANES

The Z and E isomers of the title compounds are regioselectively and stereoselectively prepared respectively by reaction of phosphorus ylides with α-selenocyclopropyl aldehydes and by addition of α-lithio seleno-cyclopropanes on α-seleno aldehydes.