78824-18-7Relevant academic research and scientific papers
STUDY OF THE REACTION OF SODIUM AMIDE IN LIQUID AMMONIA WITH HEXAHYDRO-(1H)-2-BENZAZONINIUM SALTS: ACCESS TO 2-AZA-(7)-METACYCLOPHANES
Barbry, Didier,Spanneut, Damien,Hasiak, Bruno,Couturier, Daniel
, p. 47 - 52 (2007/10/02)
The rearrangement of hexahydro-(1H)-2-benzazoninium ylides in liquid ammonia yields a mixture of amines: metacyclophanes arise from Sommelet-Hauser transposition, alkenes from an Hofmann elimination, enamines from a process which is discussed here, and tw
