78839-98-2

Basic information

• Product Name: Benzene, [[5-(1,1-dimethylethyl)-2-methyl-1-cyclohexen-1-yl]thio]-
• CAS NO: 78839-98-2
• Molecular Formula: C17H24S
• Molecular Weight: 260.444
• Mol File: 78839-98-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [[5-(1,1-dimethylethyl)-2-methyl-1-cyclohexen-1-yl]thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[5-(1,1-dimethylethyl)-2-methyl-1-cyclohexen-1-yl]thio]-(78839-98-2)
• EPA Substance Registry System: Benzene, [[5-(1,1-dimethylethyl)-2-methyl-1-cyclohexen-1-yl]thio]-(78839-98-2)

Safety Data

• Hazardous Substances Data: 78839-98-2(Hazardous Substances Data)

Upstream product

• 60774-46-1 4-tert-butyl-2-phenylsulfanylcyclohexanone 
• 882-33-7 diphenyldisulfane 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 75-24-1 trimethylaluminum 
• 78839-97-1 4-t-butyl-2-phenylthio-1-cyclohexenyl diphenyl phosphate 

Downstream Products

• 56569-76-7 2-methyl-5-tert-butylcyclohexanone 

Relevant articles and documents

CROSS-COUPLING REACTION BETWEEN ENOL PHOSPHATES AND ORGANOALUMINIUM COMPOUNDS IN THE PRESENCE OF PALLADIUM(0) CATALYST.

The title reaction in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) affords alkylative coupling products in good to excellent yields in 1,2-dichloroethane at room temperature. This coupling reaction under C(sp**2)-O cleavage proceeds stereospecifically. The reaction does not affect a coexisting vinyl sulfide group. This feature enables 1,2- and 1,3-carbonyl transposition with or without alkylation via phenylthio-substituted enol phosphates.