78840-83-2Relevant academic research and scientific papers
Neighboring Group Participation in the Pyrrole Series
Smith, Kevin M.,Martynenko, Zoya,Pandey, Ravindra K.,Tabba, Hani D.
, p. 4296 - 4302 (2007/10/02)
With use of proton and carbon-13 NMR spectroscopy of deuterium- and carbon-13-labeled substrates, the transformation of certain (2-hydroxyethyl)pyrroles (4, 18, 21) into the corresponding (2-haloethyl)pyrroles (using thionyl chloride/pyridine or triphenyl
NEIGHBORING GROUP PARTICIPATIONBY THE PYRROLE NUCLEUS
Smith, Kevin M.,Martynenko, Zoya,Tabba, Hani D.
, p. 1291 - 1294 (2007/10/02)
Using proton and carbon-13 NMR spectroscopy, the transformation of 2-hydroxyethylpyrrols (5,15) into 2-haloethylpyrroles by treatment with thionyl chloride or carbon tetrabromide/triphenylphosphine is shown to proceed by randomization of the two sidechain
