78847-41-3Relevant academic research and scientific papers
ISOMERISATIONS THERMIQUES ORIGINALES DE COMPOSES β-CHLORES DU SILICIUM INDUITES PAR UN GROUPE β'-ETHYLENIQUE
Manuel, Georges,Bertrand, Guy,Mazerolles, Pierre,Ancelle, Jacques
, p. 311 - 323 (2007/10/02)
The thermolysis of linear and cyclic β-chloro-β'-ethylenesilicon compounds gives rise to two competitive reactions.Besides the classical β-elimination reaction, a new rearrangement reaction was observed, which depends on the Si-bonded R groups; it has not been noticed for the corresponding germanium compounds.To explain the results, we propose a mechanism involving a transient pentavalent silicon anion.
