78887-85-1Relevant academic research and scientific papers
ORGANOTIN HYDRIDE ADDITIONS TO E- AND Z-TRISUBSTITUTED ETHYLENES.SYNTHESIS OF SOME NEW FUNCTIONALLY SUBSTITUTED ORGANOTIN COMPOUNDS
Podesta, J. C.,Chopa, A. B.,Ayala, A.D.
, p. 163 - 170 (2007/10/02)
The syntheses of some new functionally substituted organotin compounds are reported.The results indicate that the additions of tri-n-butyltin and tri-phenyltin hydrides to trisubstituted ethylenes (where one substituent is either a carbomethoxy or a nitrile group) proceed smoothly to give high yields of organotin adducts and that the reactions are stereoselective.Evidence concerning the reversibility of the free radical forming step is presented.
