78887-98-6

Basic information

• Product Name: (C₆H₅)ISn(SC₂H₄)2O
• CAS NO: 78887-98-6
• Molecular Weight: 458.959
• Mol File: 78887-98-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₆H₅)ISn(SC₂H₄)2O(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)ISn(SC₂H₄)2O(78887-98-6)
• EPA Substance Registry System: (C₆H₅)ISn(SC₂H₄)2O(78887-98-6)

Safety Data

• Hazardous Substances Data: 78887-98-6(Hazardous Substances Data)

Upstream product

• 14532-07-1 phenyl tin ⁽³⁺⁾; tris iodide 
• 2150-02-9 bis(2-mercaptoethyl)ether 

Relevant articles and documents

UEBER ZINN-HALTIGE HETEROCYCLEN. V. Sn-PHENYL-SUBSTITUIERTE STANNOCANE, UEBERGAENGE VON TETRAEDRISCHER 4-ZU TRIGONAL-BIPYRAMIDALER 5-KOORDINATION

A complete series of diphenyl and mixed methyl/chlorine/bromine/iodinephenyl substituted oxadithia- and trithiastannocanes has been prepared by reactions between the respective disodium dithiolates and tin dihalides.The 13C NMR chemical shifts of these compounds and the coupling constants J(119Sn-13C) are dependent upon the magnetic anisotropy of the substituents and the bond angles at the tin atom.The crystal structure of 2,2-diphenyl-1,3,6-trithia-2-stannocane has been determined and refined to R=0.039.The environment of Sn is a monocapped tetrahedron (transannular distance Sn...S 324.6(1) pm).This type of coordination, intermediate between a tetrahedron and a trigonal bipyramid, is discussed quantitatively and compared with a series of analogous compounds.The eight-membered ring has the boat-chair conformation.