78905-89-2Relevant academic research and scientific papers
An efficient and rapid chalcogenide-Morita-Baylis-Hillman process promoted by TBDMSOTf and a thiolane
Rao, Jamjanam Srivardhana,Brière, Jean-Fran?ois,Metzner, Patrick,Basavaiah, Deevi
, p. 3553 - 3556 (2007/10/03)
The ability of the combination of sulfide/TBDMSOTf to promote a chalcogenide-Morita-Baylis-Hillman reaction is reported. The original Michael-Mukaiyama-retroaldol sequence took place and furnished the MBH adducts from the corresponding enones and acetals.
A simple procedure for α-alkoxyalkylation of α,β-enones via pyridiniosilylation
Kim,Kim,Park
, p. 2043 - 2044 (2007/10/02)
A one-pot, three-step procedure for α-alkoxyalkylation of α,β-enones utilizing a new pyridiniosilylation reaction is described.
TRIMETHYLSILYL TRIFLATE IN ORGANIC SYNTHESIS
Noyori, R.,Murata, S.,Suzuki, M.
, p. 3899 - 3910 (2007/10/02)
Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media.The reactions proceed via one-center, electrophilic coordination of the silyl group to hetero functional groups and exhibit unique selectivities.
A NEW PROCEDURE FOR α-ALKOXYALKYLATION OF α,β-UNSATURATED KETONES
Suzuki, M.,Kawagishi, T.,Noyori, R.
, p. 1809 - 1812 (2007/10/02)
A one-pot procedure for α-alkoxyalkylation of α,β-unsaturated ketoneshas been devised, which by combination with the organocopper conjugate addition reaction provides a new tool for vicinal carba-condensation of enones.
