78905-90-5Relevant academic research and scientific papers
TRIMETHYLSILYL TRIFLATE IN ORGANIC SYNTHESIS
Noyori, R.,Murata, S.,Suzuki, M.
, p. 3899 - 3910 (1981)
Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media.The reactions proceed via one-center, electrophilic coordination of the silyl group to hetero functional groups and exhibit unique selectivities.
A NEW PROCEDURE FOR α-ALKOXYALKYLATION OF α,β-UNSATURATED KETONES
Suzuki, M.,Kawagishi, T.,Noyori, R.
, p. 1809 - 1812 (2007/10/02)
A one-pot procedure for α-alkoxyalkylation of α,β-unsaturated ketoneshas been devised, which by combination with the organocopper conjugate addition reaction provides a new tool for vicinal carba-condensation of enones.
