78925-90-3

Basic information

• Product Name: 2-Acetoxy-2-cyclohex-1-enylmethyl-malonic acid diethyl ester
• Synonyms: 2-Acetoxy-2-cyclohex-1-enylmethyl-malonic acid diethyl ester
• CAS NO: 78925-90-3
• Molecular Weight: 312.363
• Mol File: 78925-90-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Acetoxy-2-cyclohex-1-enylmethyl-malonic acid diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Acetoxy-2-cyclohex-1-enylmethyl-malonic acid diethyl ester(78925-90-3)
• EPA Substance Registry System: 2-Acetoxy-2-cyclohex-1-enylmethyl-malonic acid diethyl ester(78925-90-3)

Safety Data

• Hazardous Substances Data: 78925-90-3(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 1192-37-6 methylenecyclohexane 
• 609-09-6 Diethyl ketomalonate 

Downstream Products

• 27338-39-2 diethyl (1-cyclohexenylmethyl)malonate 

Relevant articles and documents

GENERATION OF ESTER ENOLATES BY REDUCTIVE α-DEACETOXYLATION

Diethyl allylmalonates or 2 arylalkanoic esters are prepared in good yield by reductive α-deoxygenation of the corresponding α-acetoxy or α-alkoxy esters.Since the intermediate ester enolates are generated under aprotic conditions, a one pot reductive-alkylation is also possible.One application of this procedure allows diethyl oxomalonate to serve as a conjunctive reagent for stitching together an alkene and an alkyl halide with a malonyl group as linchpin.