78944-63-5

Basic information

• Product Name: poly(1,2-ethylenepiperidine) N-oxide
• Synonyms: poly(1,2-ethylenepiperidine) N-oxide
• CAS NO: 78944-63-5
• Molecular Formula: (C7H13 N O)n
• Molecular Weight: 0
• Mol File: 78944-63-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: poly(1,2-ethylenepiperidine) N-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: poly(1,2-ethylenepiperidine) N-oxide(78944-63-5)
• EPA Substance Registry System: poly(1,2-ethylenepiperidine) N-oxide(78944-63-5)

Safety Data

• Hazardous Substances Data: 78944-63-5(Hazardous Substances Data)

Upstream product

• 134256-32-9 N-benzyl-2-(2-hydroxyethyl)piperidine 

Relevant articles and documents

Catalytic Asymmetric Synthesis of N-Chiral Amine Oxides

Direct asymmetric synthesis of N-chiral amine oxides was accomplished (up to 91:9 e.r.) by means of a bimetallic titanium catalyst. A hydroxy group situated at the γ-position of the N stereocenter enables the desired N-oxidation through dynamic kinetic resolution of the trivalent amine substrates. The method was further extended to the kinetic resolution of racemic γ-amino alcohols with a preexisting stereocenter, giving an important class of enantioenriched (up to 99.9:0.1 e.r.) building blocks that are otherwise difficult to synthesize.