78962-19-3Relevant academic research and scientific papers
Oxidation by DMSO. II. An efficient synthesis of α,β-diketones from α,β-dibromides
Villemin,Hammadi
, p. 3145 - 3148 (2007/10/02)
α,β-Dibromides refluxed in DMSO are oxidised into α,β-diketones. The reaction takes place rapidly under microwave irradiation.
OXIDATION OF N-ALKYL-N'-TOSYLHYDRAZINES WITH BROMINE
Palmieri, Gianni
, p. 4097 - 4102 (2007/10/02)
Oxidation of N-alkyl-N'-tosylhydrazines with bromine yield alkyl bromides, vicinal alkyl dibromides and traces of alcohols.The main products of primary hydrazines are monobromides whereas secondary hydrazines preferably produce dibromides.The reaction proceeds with evolution of nitrogen and hydrobromic acid and by the formation of intermediate sulfinic ester wich may be isolated.Various substrates were examined under different conditions to confirm the validity of the reaction mechanism hypothesized.
