78969-86-5Relevant academic research and scientific papers
A NEW ROUTE TO SUBSTITUTED VANADIUM CARBONYL ANIONS. SYNTHESES OF ALKYL AND ARYL ISOCYANIDEPENTACARBONYLVANADATE(1-) COMPLEXES, V(CO)5CNR-
Ellis, John E.,Fjare, Kristi Lenz
, p. C33 - C35 (1981)
Aminepentacarbonylvanadate(1-) ion undergoes thermal substitution in the presence of ? acceptor ligands to provide high yields (65-85percent) of V(CO)5L-.By this method , containing an unligated PPh2, and the first examples of the isocyanide substituted anions -, where R = Me, t-Bu, cyclohexyl and phenyl have been prepared.This new method provides only monosubstituted carbonylvanadate(1-) ions and is especially important when such products are unavailable or not readily preparable by photochemical means.
