78998-84-2Relevant academic research and scientific papers
Dual Nature of (Phenylseleno)cobaloxime in the Reaction with 2-Propynyl Derivatives
Tada, Masaru,Nagasaka, Ritsuko
, p. 3221 - 3226 (2007/10/03)
Photolysis or thermolysis of (phenylseleno)cobaloxime gives a pair of radicals: phenylseleno radical and cobaloxime radical, which are considered to be equilibrated with the ion pair by a single electron transfer. the radical addition on the acetylenic moiety takes place when the 2-propynyl derivatives have weak leaving groups (OH, OPh, OAc).On the other hand, the ionic substitution with phenylseleno anion takes place on bromies and tosylates.
SELECTIVE OXIDATION OF HYDROXY GROUPS OF PHENYLTHIO AND PHENYLSELENO ALCOHOLS
Shimizu, Makoto,Urabe, Hirokazu,Kuwajima, Isao
, p. 2183 - 2186 (2007/10/02)
Various kinds of alcohols bearing phenylthio or phenylseleno moiety were converted into the corresponding carbonyl compounds in good to excellent yields by treating with dimesityl diselenide and tert-butyl hydroperoxide.
