79012-27-4Relevant academic research and scientific papers
Reactions of Propargyl Alcohols. VII. Lithium Aluminium Hydride Reductions of 1-Methoxy-2-phenylpent-3-yn-2-ol, 1 Methoxy-3-phenylhex-4-yn-3-ol and 7-Methoxy-4-phenylhept-2-yn-4-ol
Blunt, John W.,Hartshorn, Michael P.,Soong, Lee Tin,Munro, Murray H. G.,Vannoort, Richard W.,Vaughan, John
, p. 1387 - 1398 (2007/10/02)
Lithium aluminium hydride reductions in ether solvents of 1-methoxy-2-phenylpent-3-yn-2-ol (7a), 1-methoxy-3-phenylhex-4-yn-3-ol (7b) and 7-methoxy-4-phenylhept-2-yn-4-ol (7c) are reported.Evidence for methoxy group participation in the reduction process
CYCLOPROPANE DERIVATIVES FROM THE LITHIUM ALUMINIUM HYDRIDE REDUCTION OF METHOXYALKYNOLS
Blunt, J. W.,Hartshorn, M. P.,Munro, M. H. G.,Soong, Lee Tin,Vannoort, R. W.
, p. 2143 - 2144 (2007/10/02)
Lithium aluminium hydride reduction of methoxyalkynol (1) yields cyclopropane derivates (2) and (3), both formed by loss of a methoxy group; a reaction scheme for their formation is presented.
