79019-69-5Relevant academic research and scientific papers
Electron-rich cations: Preparation and hydride reductions of the cations {(η5-C5H5)Ru[MeC(CH2PPh 2)3]}+ and {(η5-C5H5)Ru[PhP(CH2CH
Davies, Stephen G.,Simpson, Stephen J.,Felkin, Hugh,Fillebeen-Khan, Tauqir
, p. 539 - 541 (2008/10/08)
The cations {(η5-C5H5)Ru[MeC(CH2PPh 2)3]}+ and {(η5-C5H5)Ru[PhP(CH2CH 2PPh2)2]}+ are reduc
Davies, Stephen G.,Simpson, Stephen J.,Felkin, Hugh,Fillebeen-Khan, Tauqir
, p. 539 - 541 (2008/10/08)
The cations {(η5-C5H5)Ru[MeC(CH2PPh 2)3]}+ and {(η5-C5H5)Ru[PhP(CH2CH 2PPh2)2]}+ are reduc
Hydride Reduction of the Cations 5-C5H5)Fe>PF6, 5-C5H5)Ru>PF6, and 5-C5H5)Ru>PF6: Regioselectivity and Mechanism
Davies, Stephen G.,Felkin, Hugh,Fillebeen-Khan, Tauqir,Tadj, Fatemeh,Watts, Oliver
, p. 341 - 342 (2007/10/02)
Reduction of the cation 5-C5H5)Fe(tripod)>PF6 with lithium aluminium hydride gives (η5-C5H5)FeH(tripod) via an SN1 mechanism, involving prior dissociation of a phosphine ligand leading to direct attack of hydride on the metal, in contrast with the related ruthenium cations 5-C5H5)RuL3>PF6 (L3 = triphos or tripod) which give the cyclopentadiene complexes (η4-C5H6)RuL3 via exo-hydride attack on the cyclopentadienyl ligand .
