790227-69-9Relevant academic research and scientific papers
Organosilanes in copper-mediated conjugate reductions and reductive aldol reactions
Chiu, Pauline
, p. 2210 - 2215 (2004)
Organosilanes have been used to synthesize and regenerate copper hydrides, and have been employed as stoichiometric reductants in the copper-catalyzed reductions of a variety of activated olefins. Reductive aldol condensations and cyclizations using organosilanes and transition metal catalysts, including copper hydrides, have also been achieved.
Stoichiometric and catalytic reductive aldol cyclizations of alkynediones induced by Stryker's reagent
Chiu, Pauline,Leung, Sze Kar
, p. 2308 - 2309 (2007/10/03)
Conjugate reduction of alkynones by stoichiometric [(Ph3P)CuH] 6 or catalytic [(Ph3P)CuH]6 and polymethylhydrosiloxane proceeds to cyclization by an aldol reaction with tethered ketones to generate β-hydroxyenon
