79032-37-4Relevant academic research and scientific papers
Hetero-Diels-Alder reactions of 2H-phospholes with aldehydes
Toullec, Patrick,Ricard, Louis,Mathey, Francois
, p. 2803 - 2806 (2003)
Transient 2-phenyl-3,4-dimethyl-5H-phosphole reacts at 150 °C with aldehydes RCH=O to give the corresponding [4 + 2] P-O cycloadducts with endo- b(major) and exo-R-substituents. The cycloaddition with α,β-unsaturated aldehydes takes place both at the C=O
A new versatile route for the conversion of phospholes into phosphinines
Wang, Huaiqiu,Li, Chuan,Geng, Dingjin,Chen, Hui,Duan, Zheng,Mathey, Francois
supporting information; experimental part, p. 10659 - 10661 (2010/11/18)
(Figure Presented) En route to phosphinines: An efficient route to convert 1-phosphanorbornadienes into phosphinines is described (see scheme). This opens up the possibiltiy to use the broad and versatile phosphole chemistry as a starting point for an equ
3,4-dimethyl-2,5,6-tris(p-sulfonatophenyl)-1-phosphanorbornadiene, process for the preparation thereof and process for the hydroformylation of olefinnically unsaturated compounds
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, (2008/06/13)
The chemical compound 3,4-dimethyl-2,5,6-tris(p-sulfonatophenyl)-1-phosphanorbernadiene, a process for the preparation thereof and a process for the hydroformylation of olefinically unsaturated compounds with the use of catalysts which contain the aforeme
