79033-74-2Relevant academic research and scientific papers
Rearrangements of Vinylogous Acyl Chlorides, XXIX. - 1,5-Pentadiene-Oxygen Transfer of (Z)-2,4,5,5-Tetrachloro-3-organylthio- and (Z,Z)-2,3,4,5-Tetrachloro-5-organylthio-2,4-pentadienethioates
Roedig, Alfred,Fleischmann, Klaus,Frank, Fritz,Rettenberger, Reinhard
, p. 858 - 869 (2007/10/02)
The title compounds 2 and 10 are prepared from the thioates 1 and from the acyl chlorides 9, respectively, with thiolates in ethanol or ether.The position of the thio group in 2 is determined by hydrolysis to 5a and oxidation to 6a which can also be obtai
