790698-11-2

Upstream product

• 227186-05-2 (1'R,2R,5R)-5-(hydroxymethyl)-2-<(1'-methoxymethoxy)tridecyl>tetrahydrofuran 
• 790698-09-8 2-(S)-benzyloxymethyl-5-(S)-{1-(S),4-(R)-bis-methoxymethoxy-4-[5-(R)-(1-(R)-methoxymethoxy-tridecyl)tetrahydrofuran-2-(R)-yl]but-2-ynyl}-2,5-dihydrofuran 
• 790698-08-7 4-(5-(S)-benzyloxymethyl-2,5-dihydrofuran-2-(S)-yl)-4-(S)-methoxymethoxy-1-[5-(R)-(1-(R)-methoxymethoxy-tridecyl)tetrahydrofuran-2-(R)-yl]but-2-yn-1-(R)-ol 
• 790698-16-7 (R)-4-Benzyl-3-[(2S,3R)-2-((R)-1-benzyloxymethyl-allyloxy)-3-methoxymethoxy-pentadecanoyl]-oxazolidin-2-one 
• 790698-10-1 (5-(S)-{1-(S),4-(R)-bis-methoxymethoxy-4-[5-(R)-(1-(R)-methoxymethoxy-tridecyl)tetrahydrofuran-2-(R)-yl]butyl}tetrahydrofuran-2-(S)-yl)methanol 
• 790698-04-3 4-(R)-benzyl-3-{2-(S)-[1-(R)-benzyloxymethyl-allyloxy]-3-(R)-hydroxy-pentadecanoyl}oxazolidin-2-one 
• 790698-15-6 (S)-4-Benzyl-3-[(2R,3S)-2-((S)-1-benzyloxymethyl-allyloxy)-3-methoxymethoxy-5-triisopropylsilanyl-pent-4-ynoyl]-oxazolidin-2-one 
• 790697-99-3 4-(S)-benzyl-3-{2-(R)-[1-(S)-benzyloxymethyl-allyloxy]-3-(S)-hydroxy-5-triisopropylsilanyl-pent-4-ynoyl}oxazolidin-2-one 
• 790697-96-0 2-[3-(tert-butyl-diphenyl-silanyloxy)-2-(S)-(4-methoxy-benzyloxy)-propyl]acrylic acid 1-(S)-methyl-allyl ester 
• 790698-05-4 2-(R)-[1-(R)-benzyloxymethyl-allyloxy]-3-(R)-methoxymethoxy-pentadecan-1-ol 
• 790698-06-5 {2-(R)-[1-(R)-(1-(R)-methoxymethoxy-tridecyl)allyloxy]but-3-enyloxymethyl}benzene 
• 790697-97-1 3-[3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)propyl]-5-methyl-5H-furan-2-one 
• 790698-13-4 2-[3-(tert-butyl-diphenyl-silanyloxy)-2-(S)-(4-methoxy-benzyloxy)propyl]acrylic acid 
• 790698-07-6 2-(R)-benzyloxymethyl-5-(R)-[1-(R)-methoxymethoxy-tridecyl]-2,5-dihydrofuran 

Downstream Products

• 790698-17-8 (S)-3-[(R)-7-((2R,5S)-5-{(1S,4R)-1,4-Bis-methoxymethoxy-4-[(2R,5R)-5-((R)-1-methoxymethoxy-tridecyl)-tetrahydro-furan-2-yl]-butyl}-tetrahydro-furan-2-yl)-2-(4-methoxy-benzyloxy)-heptyl]-5-methyl-5H-furan-2-one 
• 130818-48-3 (+)-gigantecin 

Relevant academic research and scientific papers

Enantioselective total synthesis of (+)-gigantecin: Exploiting the asymmetric glycolate aldol reaction

The enantioselective synthesis of the potent, selective, cytotoxic, annonaceous acetogenin, (+)-gigantecin, has been completed. An asymmetric glycolate aldol serves to establish the stereocenters at C13,14 and at C21,22. A Carreira asymmetric acetylide ad