790699-61-5

Upstream product

• 78-38-6 ethylphosphonic acid diethyl ester 
• 166194-08-7 methyl 3-<(tert-butyldiphenylsilyl)oxy>propionate 
• 127047-71-6 3-(tert-butyldiphenylsilyloxy)propan-1-ol 

Downstream Products

• 790699-91-1 {2-[(4R,5R,6S)-6-((S)-4-Benzyloxy-hexyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-ethoxy}-tert-butyl-diphenyl-silane 
• 790699-87-5 (3R,4R,5S,9S)-9-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-4-methyl-undecane-3,5-diol 
• 790699-83-1 (R)-1-[(2S,3S)-3-((S)-4-Benzyloxy-hexyl)-2-methyl-oxiranyl]-3-(tert-butyl-diphenyl-silanyloxy)-propan-1-ol 
• 790699-79-5 (E)-(3R,9S)-9-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-4-methyl-undec-4-en-3-ol 
• 790699-70-6 (E)-(S)-9-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-4-methyl-undec-4-en-3-ol 
• 790699-97-7 [(4R,5R,6S)-6-((S)-4-Benzyloxy-hexyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-acetic acid methyl ester 
• 790699-95-5 2-[(4R,5R,6S)-6-((S)-4-Benzyloxy-hexyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-ethanol 
• 790700-01-5 (4R,5S,6S)-6-((S)-4-Benzyloxy-hexyl)-4-hydroxy-5-methyl-tetrahydro-pyran-2-one 
• 790699-65-9 (E)-(S)-9-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-4-methyl-undec-4-en-3-one 

Relevant academic research and scientific papers

Synthesis of (3R,4S,5S,9S)-3,5,9-trihydroxy-4-methylundecanoic acid δ-lactone

Radical-mediated opening of a chiral trisubstituted epoxy alcohol using cp2TiCl furnished the '2-methyl-1,3-diol' moiety with the desired stereochemistry, which led to a total synthesis of (3R,4S,5S,9S)-3,5,9- trihydroxy-4-methylundecanoic acid