791-30-0Relevant academic research and scientific papers
Boron-metal exchange reaction of silylboranes with organometallic reagents: A new route to arylsilyl anions
Kawachi, Atsushi,Minamimoto, Takashi,Tamao, Kohei
, p. 1216 - 1217 (2007/10/03)
The boron-metal exchange reaction of (arylsilyl)boranes with alkyllithiums, potassium tert-butoxide, and methylmagnesium bromide affords the corresponding silyllithium, silylpotassium, and silylmagnesium compounds, respectively. Especially, the boron-lithium exchange reaction occurs even in hydrocarbon solvents such as toluene and hexane as well as in THF.
Alkylation and acylation of some activated aromatic substrates by organosilicon compounds
Artamkina, G. A.,Kovalenko, S. V.,Beletskaya, I. P.,Reutov, O. A.
, p. 139 - 150 (2007/10/02)
A method of alkylation and acylation of trinitrobenzene employing the oxidation of anionic ?-complexes generated from organosilicon reagents in the presence of KF/18-crown-6 ether is described.The method enables the introduction of alkyl and acyl substitu
