791069-13-1

Basic information

• Product Name: [(2,6-Me₂C₆H₃NC(Me)CHC(Me)NC₆H₃-2,6-Me₂)Cu(2,4-lutidine)]
• CAS NO: 791069-13-1
• Molecular Weight: 476.144
• Mol File: 791069-13-1.mol

Chemical Properties

• CAS DataBase Reference: [(2,6-Me₂C₆H₃NC(Me)CHC(Me)NC₆H₃-2,6-Me₂)Cu(2,4-lutidine)](CAS DataBase Reference)
• NIST Chemistry Reference: [(2,6-Me₂C₆H₃NC(Me)CHC(Me)NC₆H₃-2,6-Me₂)Cu(2,4-lutidine)](791069-13-1)
• EPA Substance Registry System: [(2,6-Me₂C₆H₃NC(Me)CHC(Me)NC₆H₃-2,6-Me₂)Cu(2,4-lutidine)](791069-13-1)

Safety Data

• Hazardous Substances Data: 791069-13-1(Hazardous Substances Data)

Upstream product

• 386273-06-9 Tl((CH₃)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH₃)2) 

Downstream Products

• 791069-15-3 (((CH₃)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH₃)2)Cu)2 

Relevant articles and documents

Cu(I) β-diketiminates for alkene aziridination: Reversible Cu-arene binding and catalytic nitrene transfer from PhI=NTs

β-Diketiminato Cu(I)-lutidine complexes [RMeNN]Cu(2,4-lutidine) (R = Me (4a), iPr (4b)) were prepared in high yield from Tl[RMeNN] and [CuBr(2,4-lutidine)2]2. Both 4a and 4b reversibly dissociate lutidine base in toluene to give [RMeNN]Cu(toluene) solvento complexes. A related base-free dicopper species {[Me2NN]Cu} 2 (6) bridged via η2-binding of opposing N-aryl rings could be isolated by the addition of Tl[Me2NN] to CuBr. The lutidine precursors serve as precatalysts for the aziridination of alkenes with PhI=NTs. Styrene, β-methylstyrene, and cyclooctene gave the highest yields (59-96%) with a low olefin to PhI=NTs ratio (3:1) and 5 mol % catalyst loading.