79111-71-0

Upstream product

• 74-93-1 methylthiol 
• 64608-21-5 2-(3,3-bis(methylthio)-1-phenylallylidene)malononitrile 
• 86840-08-6 2-(2-Bromo-3,3-bis-methylsulfanyl-1-phenyl-allylidene)-malononitrile 
• 109-77-3 malononitrile 
• 105-56-6 ethyl 2-cyanoacetate 

Downstream Products

• 133615-19-7 3-Benzylideneamino-6-benzylidenhydrazino-4-phenyl-1H-pyrazolo<3,4-b>-pyridin 
• 133615-17-5 6-Methanesulfonyl-4-phenyl-1H-pyrazolo[3,4-b]pyridin-3-ylamine 
• 94924-68-2 5-Bromo-2,6-diethoxy-4-phenyl-nicotinonitrile 
• 85149-59-3 6-Hydrazino-4-phenyl-1H-pyrazolo[3,4-b]pyridin-3-ylamine 
• 126168-81-8 2,6-Diethoxy-4-phenyl-nicotinonitrile 
• 85149-56-0 2,6-Bis-methanesulfonyl-4-phenyl-nicotinonitrile 
• 91272-01-4 5-Bromo-2,6-bis-methylsulfanyl-4-phenyl-nicotinonitrile 

Relevant academic research and scientific papers

2-pheny-3-(5,6,7,7a-tetrahydro-1H,3H-pyrrolo[1,2-c]oxazol-3-ylidene)-1- propene-1,1-dicarbonitrile and 4-(4-methoxyphenyl)-2,6-bis(methylthio)pyridine-3-carbonitrile

The reaction of 3-aryl-2-cyano-5,5-bis(methylthio)penta-2,4-dienenitrile, (1), with L-(-)-2-hydroxymethylpyrrolidine, (2), gave two types of product, the normal substitution product, (3), and a pyridine derivative, (4). The structures of two representativ

Push-Pull-Butadienes. VI. Synthesis of Substituted Nicotinonitriles

2-Aryl-4,4-bis(methylthio)-1,3-butadiene-1,1-dicarbonitriles 1 react with N-bromo-succinimide or sulphuryl chloride to give 3-bromo- and 3-chlorobutadienedicarbonitriles 3, respectively.Compounds 1 or 3 can be converted with methanethiol in alkaline solut

Push-pull-Butadienes. II. Reactions of 2-Aryl-4,4-bis(methylthio)-1,3-butadiene-1,1-dicarbonitriles with Malononitrile and Ethyl Cyanoacetate

2-Aryl-4,4-bis(methylthio)-1,3-butadiene-1,1-dicarbonitriles 1 react with sodium salts of malononitrile or ethyl cyanoacetate 3 to give 4-aryl-2-methylthio-1,4-pentadiene-1,1,5,5-tetracarbonitriles and ethyl-4-aryl-1,5,5-tricyano-2-methylthio-1,4-pentadienecarboxylates 4, respectively.Also, arylethylidenemalononitriles 5 and bis(methylthio)methylenemalononitrile or ethyl bis(methylthio)methylenecyanoacetate 6 afford 4.Substituted dihydropyridines 8 are prepared by treating 4 with aromatic amines.Compounds 4d, e can be converted to 2-amino-6-aryl-4-methylthiobenzene-1,3-dicarbonitriles 11a, b.