791120-06-4Relevant articles and documents
Preparation of 1-aryl-2-bromo-3,3-difluorocyclopropenes
Lin, Shaw-Tao,Chen, Li-Chwen,Lee, Chun-Jen
, p. 353 - 355 (2007/10/03)
1-Aryl-2-bromo-3,3-difluorocyclopropanes were prepared from the reaction of 2′,2′-difluorostyrene and dibromocarbene instead of from 1-aryl-2-haloacetylenes and difluorocarbene. These results are rationalised by the energy gap between HOMO(styrene), HOMO(acetylene) and LUMO(CX2). The title compounds were converted to methyl arylpropynoate in MeOH solution in quantitative yield.